Table 13. Concentrations (g/g) of Cr, Cu, Zn, As, and
Table 14. Concentrations (g/g) of Co, Ni, Hg, Se, and Fe
Pb determined by fundamental parameter analysis
determined by fundamental parameter analysis using
using the Spectrace 9000.
the Spectrace 9000.
Metal concentrations (g/g)
Metal concentrations (g/g)
Material & spike
Cu
Zn
As
Pb
Cr
Material & spike
Co
Ni
Hg
Se
Fe
Ottawa sand
Ottawa sand
1000 ppm
1430
1320
1380
976
3010
1000 ppm
1830
1538
1010
1240
ND
500 ppm
731
652
389
531
1120
500 ppm
994
846
781
637
79
250 ppm
270
287
335
274
580
250 ppm
442
427
228
307
67
125 ppm
102
152
51
131
310
125 ppm
109
183
380
143
120
0 ppm
ND
ND
ND
ND
ND
0 ppm
ND
ND
111
ND
118
Matrix
ND
ND
10
ND
ND
Matrix
ND
ND
ND
ND
1420
Ft. Edwards clay
Ft. Edwards clay
1000 ppm
1340
1140*
1020 1020
850
1000 ppm
727*
999
791
1100
55,400
500 ppm
532
524*
660 467
300
500 ppm
277*
495
458
503
54,600
250 ppm
334
192*
343 225
ND
250 ppm
67*
207
200
265
56,700
125 ppm
227
147*
13 138
ND
125 ppm
ND*
12
360
120
57,000
0 ppm
131
99
ND ND
ND
0 ppm
560
ND
80
ND
55,600
Matrix
67
99
66 ND
ND
Matrix
406
ND
ND
ND
56,900
CRREL soil
CRREL soil
1000 ppm
1130
1270*
1280 1040
940
1000 ppm
965*
1210
1321
1350
40,000
500 ppm
489
550*
656 657
57
500 ppm
295*
624
665
611
40,900
250 ppm
253
221*
311
232
53
250 ppm
235*
216
259
332
41,100
125 ppm
77
120*
60 172
ND
125 ppm
315*
148
155
146
41,100
0 ppm
ND
74
ND ND
ND
0 ppm
190
11
95
ND
41,300
Matrix
ND
95
56 ND
ND
Matrix
280
ND
16
ND
40,900
Rocky Mountain Arsenal
Rocky Mountain Arsenal
1000 ppm
1280
1240
1350 1170
1480
1000 ppm
1490
1480
1170
1390
18,600
500 ppm
678
675
636 589
440
500 ppm
900
786
736
689
19,600
250 ppm
236
333
375 281
280
250 ppm
479
324
301
304
22,500
125 ppm
74
125
19 141
120
125 ppm
224
141
579
140
21,700
0 ppm
ND
ND
22 ND
ND
0 ppm
ND
ND
121
ND
21,100
Matrix
ND
36
28 ND
ND
Matrix
ND
ND
ND
ND
20,100
Tampa Bay sediments
Tampa Bay sediments
1000 ppm
1210
1250
1230 1100
1490
1000 ppm
1710
1720
1350
1310
4410
500 ppm
662
545
651 477
700
500 ppm
738
687
728
758
4240
250 ppm
312
289
278 256
120
250 ppm
423
308
356
350
3930
125 ppm
70
118
63
83
ND
125 ppm
198
152
529
185
3470
0 ppm
ND
ND
12 ND
66
0 ppm
122
32
151
ND
3500
Matrix
ND
ND
23 ND
ND
Matrix
24
ND
ND
ND
4190
Lebanon landfill soil
Lebanon landfill soil
1000 ppm
1130
1130
1110 1130
1350
1000 ppm
1330
1280
1040
1260
24,900
500 ppm
584
613
567 460
450
500 ppm
660
578
744
705
25,900
250 ppm
316
327
332 218
150
250 ppm
208
294
227
346
25,500
125 ppm
71
133
59 130
ND
125 ppm
160
119
336
134
27,200
0 ppm
ND
13
11 ND
ND
0 ppm
ND
ND
151
ND
25,600
Matrix
ND
22
43 ND
ND
Matrix
109
14
ND
ND
25,700
* Average of 0 ppm and matrix subsamples subtracted
* Average of 0 ppm and matrix subsamples subtracted
is the depth of penetration achieved by the inci-
ranges from 40 mm for Am-241 to 4.8 mm for Cd-
dent radiation, i.e., how much of the sample is ac-
109. The combination of these factors controls the
tually analyzed. The penetration depth of incident
intensity that will be measured for a given element.
radiation is inversely proportional to its wave-
For example, Table 6 shows the range of analyte
length and directly proportional to its energy. For
intensities obtained for the same concentration in
the sources used in this study, the depth of pen-
the RMA soil.
To illustrate the combination of these two ef-
10