3. Aside from permeability, the pressure-saturation relation for fluids in porous media is
the most critical physical function for modeling the transport of fluids in variably saturated
media. It has yet to be resolved entirely how temperature affects this relationship. A satis-
factory understanding of the effect of temperature on soil retention curves for water and
other liquids must be developed.
4. A co-ordinated research effort to determine the temperature effects on the physics of
insoluble and sparingly soluble nonaqueous phase liquids in porous media should be pur-
sued.
5. In frozen ground, the movement of solutes and water in response to osmotic and
thermal gradients may be significant. Relations by which the transport of water, solutes,
and nonaqueous phase liquids in response to thermal and osmotic gradients may be esti-
mated reliably should be derived or developed.
CONCLUSION
A surprising number of cold-regions areas in the northern hemisphere are contaminat-
ed. There is a need to incorporate the fundamental physical, chemical, and hydrological
processes that govern contaminant hydrology into the numerical models that are used to
assist in the remediation of these sites. It is hoped this document assists in this process.
The physical and chemical processes that determine the fate of contaminants in cold
regions are just now being understood comprehensively. As with any new area of under-
standing, this is a challenging process, but it is also an exciting area at the limits of our
understanding of the dynamic behavior of complex, heterogeneous materials.
LITERATURE CITED
Archer, D.G. (1992) Thermodynamic properties of the NaCl + H2O system, 2, Thermody-
namic properties of NaCl(aq), NaCl 2H2O (cr), and phase equilibria. Journal of Physical and
Chemical Reference Data, 21: 793829.
Atkins, P.W. (1990) Physical Chemistry. New York: W.H. Freeman and Co., 4th edition.
Bates, R.E. and M.A. Bilello (1966) Defining the cold regions of the Northern Hemisphere.
USA Cold Regions Research and Engineering Laboratory, Technical Report 178.
Bureau International des Poids et Mesures (1984) Le Systme International d'Units (SI). 6th
edition. Svres, France: Bureau International des Poids et Mesures.
Callen, H.B. (1960) Thermodynamics. New York: John Wiley and Sons.
Constantz, J. (1991) Comparison of isothermal and isobaric water retention paths in non-
swelling porous materials. Water Resources Research, 27: 31653170.
Dorsey, N.E. (1940) Properties of Ordinary Water Substance. American Chemical Society. New
York: Reinhold.
Everett, D.H. (1961) The thermodynamics of frost damage to porous solids. Journal of the
Chemical Society, Faraday Transactions, 57: 15411551.
Grigull, U., J. Straub, and P. Schiebener (1984) Steam Tables in SI Units. 3rd edition. Berlin:
Springer-Verlag.
Guggenheim, E.A. (1957) Thermodynamics: An Advanced Treatment for Chemists and Physi-
cists. 3rd edition. New York: Interscience Publishers.
Haar, L., J.S. Gallagher, and G.S. Kell (1984) NBS/NRC Steam Tables. New York: Hemi-
sphere Publishing Corporation.
Hallett, J. (1963) The temperature dependence of the viscosity of supercooled water. Pro-
ceedings, Physical Society (London), 82: 1046.
Hare, D.E., and C.M. Sorenson (1987) The density of supercooled water, II. Bulk samples
cooled to the homogeneous nuceation limit. Journal of Chemical Physics, 87: 48404845.
Harned, H.S., and B.B. Owen (1958) The Physical Chemistry of Electrolytic Solutions. 3rd edi-
tion. New York: Reinhold for American Chemical Society.
Hill, P.G. (1990) A unified equation of state for H2O. Journal of Physical and Chemical Refer-
ence Data, 19: 12311274.
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