160
RDX
140
120
100
80
60
HMX
40
nitroso-RDX
20
0
2
4
6
8
10
12
14
16
18
20
0
22
Leachate Volume (I)
Figure 2. Cumulative mass of analytes leached from pots containing con-
taminated tissues.
nitroso-RDX were recovered in the leachate. Most
ing both solvent extraction and base/acid hydrol-
of the TNT was taken up by the plants or trans-
ysis. Approximately 14% of the RDX and a trace
formed by soil microbes. Only 10% of the applied
of its nitroso transformation product and 80% of
TNT was recovered from the soil as TNT and
the HMX remained. This result is similar to those
ADNTs, while only an additional 2% was recov-
reported for compost and digester sludges
ered from the tissues by both solvent extraction
(Thorne and Leggett 1999). This would be a
and base/acid hydrolysis. For the nitramines,
promising outcome for a limited remediation
27% of the applied RDX and 47% of the HMX was
scheme; however, when field capacity was
recovered from the soil, while 37% of the RDX
exceeded and leaching occurred, HMX, RDX, and
Table 2. Mass (mg) of explosives and transformation products in soils, plant tis-
sues, in-situ humification pots, and leachates after two months' irrigation with
contaminated water. Acetonitrile solvent extractions of soil, stems, leaves, and
roots, and base/acid hydrolysates of in-situ pots and roots.
TNT
4ADNT 2ADNT
2,4DANT
2,6DANT
RDX
HMX
nitroso-RDX
Clean soil with contaminated water
mg/pot *
150
nd
nd
nd
nd
150
30
nd
Soil
5.5
4.9
3.7
nd
nd
41.2
14.2
nd
% of mass
remaining
10% (sum of TNT and ADNTs)
27%
47%
Stems
nd
nd
nd
nd
nd
7.8
0.4
nd
Leaves
nd
nd
nd
nd
nd
46.5
1.7
nd
Roots
0.5
0.8
trace
nd
nd
1.4
0.5
nd
Roots b/a
nd
1.6
0.4
0.7
0.1
nd
nd
In-situ humification pots
Tissue and soil
nd
1.2
1.2
nd
nd
20.4
24
trace
Tissue + soil b/a
nd
nd
nd
nd
nd
nd
nd
nd
% of mass
remaining
2% (sum of ADNTs)
14%
80%
Leachates (two growth pots combined)
Tissue and soil
1.6
4
2
4.6
trace
155
48
16.8
% recovery
3% (sum of TNT and
57%
80% added to RDX
transformation products)
* 12 L of water contaminated with 12.4 mg/L TNT, 12.4 mg/L RDX, and 2.43 mg/L HMX.
nd = 0.4 mg.
6