Modified X-ray cell test
detected above the baseline through barriers up
A third experiment used several polyethylene
to 1 cm in thickness, even when the moisture
31-mm X-ray cells, modified so that they were
content was increased.
only 0.5, 1.0, and 1.5 cm high. Each was covered
In Table 5, the measured intensities of Pb bur-
on the bottom with a single sheet of 0.2-mil
ied beneath the air-dried CRREL soil were lower
polypropylene. After packing the modifed cells
than established in the previous experiment
with soil, they were buried in the large soil-filled
(Table 4). An explanation for this decrease in sig-
jar so that the top rim was flush with the surface.
nal intensity between experiments is that greater
The cells were buried with and without the pack-
soil densities most likely were present in the
ets of metal salts positioned beneath. With these
modified cell experiment. In addition, measure-
cells the mass (density) of soil between the
ments through the moistened soil barriers ap-
source and the metal target could be established,
peared to decrease the Pb-line intensity, and the
and soil moisture experiments could be per-
measurement of this line became inconclusive
formed.
when the barrier was increased to 1.5 cm.
Table 5 shows the manually measured peak
Table 6 shows values for both Pb and Hg
intensities for the K lines of Pb and Hg on and
based on manually measured intensities and for
beneath an air-dried soil and for Pb beneath a
instrumental measurement of Pb using a 96-s
soil of 20 and 40% moisture content. All measure-
analysis period. The targets for this experiment
ments used a 24-s analysis period, and only the
consisted of pillows containing 0.5 g of both of
CRREL soil was used. As indicated by the previ-
these metals, or just Pb. While the findings of this
ous experiment, the K lines of these metals were
experiment again indicate that both of these met-
als could be detected if present as a 0.5-g aggre-
Table 5. Measurements (24 s)
gate or larger on or near the surface, to achieve
of 0.5-g pillows of Hg and
detection at depths greater than 1.0 cm beneath
Pb uncovered and below
the soil surface, the measurement time had to be
disks of air-dried and moist
increased.
CRREL soil.
Hg
Table 6. Measurements (96 s) of Hg and Pb be-
Soil
low disks of air-dried and moist soil matrices.
Manual*
depth
Comp.†
Soil
HgK
(cm)
Manual*
Instr.†
PbK
HgK
Comp.**
(ppm)
Moisture/depth (cm)
CRREL air dried
395
180
0.0
Lebanon Landfill (mean density 1.5 g/cm3)
75
240
0.5
240
400
750
5000
AD†† / 0.5
45
250
1.0
110
170
860
2500
AD†† / 1.0
5
295
1.5
10
80
890
1400
AD†† / 1.5
410
--
920
2230
20% / 0.5
Pb
170
--
890
1200
20% / 1.0
Soil
70
--
870
1050
20% / 1.5
Manual*
depth
440
--
910
3000
40% / 0.5
Comp.†
Soil
PbK
(cm)
180
--
890
1400
40% / 1.0
70
--
830
820
40% / 1.5
CRREL air dried
Ft. Edwards clay (mean density 1.3 g/cm3)
500
250
0.0
AD†† / 0.5
280
400
760
5200
120
280
0.5
120
190
840
2700
AD†† / 1.0
65
280
1.0
20
70
860
1200
AD†† / 1.5
15
280
1.5
500
--
950
2800
20% / 0.5
CRREL 20% moisture
200
--
910
1900
20% / 1.01
80
290
0.5
50
--
890
610
20% / 1.5
15
290
1.0
380
--
960
1800
40% / 0.5
0
290
1.5
210
--
940
1200
40% / 1.0
30
--
910
690
40% / 1.5
CRREL 40% moisture
100
290
0.5
* Manually measured fluorescent energies, baseline-
40
290
1.0
corrected.
0
290
1.5
† Instrumental measurements based on Pb (mg/kg) in
soil standards.
* Manually measured fluorescent
** Compton peak.
energies, baseline-corrected.
†† Air dried.
† Compton peak.
7