2.52 mg/kg, respectively (Fig. 7a). In grid B, mean
ture contents than soils samples from shallower
concentrations declined with depth as well. Mean
depths. Whether the higher concentrations found
concentrations of HMX in grid C were again much
at 105120 cm are connected with the higher mois-
higher in the surface soil (109 mg/kg) than at
ture contents is uncertain. Remember, the deep-
depth. Concentrations of HMX in grid D were
est samples were collected differently from those
much lower in the surface (1.44 mg/kg) than in
at the surface through 60 cm because it was
the grids nearer the target and, with only one
impractical to excavate to this depth in a soil pro-
exception, undetectable in subsurface soils.
file consisting of dry sands. Thus, it is possible that
Mean concentrations from the 105- to 120-cm
some of these deep samples may have been inad-
depth in both grids A and B from sampling areas
vertently contaminated by surface material. Since
1-44 showed higher concentrations of HMX than
some individual deep samples showed no increase
samples from either the 30- to 45-cm or 45- to 60-
in concentration, while adjacent samples showed
cm depths. However, the differences were not sta-
large increases, this explanation should be consid-
tistically significant, owing to the very large varia-
ered in planning future tests.
tions in results for the 105- to 120-cm depth. The
Concentrations of RDX (Fig. 7b), TNT (Fig. 7c),
reason for this anomalous result is uncertain, but
4-AmDNT, and 2-AmDNT were largely detected
the deepest soils had substantially higher mois-
in soil from the 0- to 15-cm depth in sampling area
Table 2. Concentrations of HMX (mg/kg) by SW-846 Method 8330 at
firing range 44 (location 144).
Sample
015 cm
1530 cm
3045 cm
4560 cm
105120 cm
Grid A
1-44-1
273 (250)*
0.68
0.65
0.70
7.01
1-44-2
302
1.00
0.41
0.25
0.37
1-44-3
479
4.29
1.31 (0.81)
0.24
2.01
1-44-4
136
0.62
0.35
0.30
0.69
Mean std. dev.
295 142
1.65 1.77
0.62 0.32
0.37 0.22
2.52 3.08
14
Grid B
1-44-5
587
1.29
0.35
0.30
1.33 (1.36)
1-44-6
269
45.1
0.78
0.31
4.91 (1.36)
1-44-7
343
0.79
0.55
0.31
7.73
1-44-8
81.4 (75.1)
26.8 (49.8)
0.83
0.24
0.28
Mean std. dev.
320 246
18.5 21.5
0.63 0.22
0.29 0.03
3.12 3.29
58
Grid C
1-44-9
20.2
0.16
0.09
0.05
ND
1-44-10
36.1
0.39
0.33
0.51
0.29
1-44-11
204 (409)
10.4
2.56
0.49
1.30
1-44-12
74.3
0.21 (0.24)
ND
ND
0.45 (0.19)
Mean std. dev.
109 133
2.79 5.07
0.73 1.22
0.26 0.28
0.48 0.57
912
Grid D
1-44-13
0.45 (0.19)
ND
--
ND
ND
1-44-14
4.28
ND
ND
ND
ND
1-44-15
ND† (0.48)
0.64
ND
ND
ND
1-44-16
0.27 (1.56)
ND
ND
ND
ND
Mean std. dev.
1.44 1.92
0.16 0.32
1316
ND
ND
ND
Grand mean
173
5.1
0.50
0.23
1.53
* Duplicate subsample.
† Not detectable.
10